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pandas - Python - Delete duplicates in a dataframe based on two columns combinations?

I have a dataframe with 3 columns in Python:

Name1 Name2 Value
Juan  Ale   1
Ale   Juan  1

and would like to eliminate the duplicates based on columns Name1 and Name2 combinations.

In my example both rows are equal (but they are in different order), and I would like to delete the second row and just keep the first one, so the end result should be:

Name1 Name2 Value
Juan  Ale   1

Any idea will be really appreciated!

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By using np.sort with duplicated

df[pd.DataFrame(np.sort(df[['Name1','Name2']].values,1)).duplicated()]
Out[614]: 
  Name1 Name2  Value
1   Ale  Juan      1

Performance

df=pd.concat([df]*100000)

%timeit df[pd.DataFrame(np.sort(df[['Name1','Name2']].values,1)).duplicated()]
10 loops, best of 3: 69.3 ms per loop
%timeit df[~df[['Name1', 'Name2']].apply(frozenset, axis=1).duplicated()]
1 loop, best of 3: 3.72 s per loop

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